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<p class="MsoNormal" style="text-align:center;line-height:150%" align="center"><strong><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman";
mso-font-kerning:0pt">张海娇教授课题组在低维能源纳米材料方面取得新进展</span></strong><strong><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt" lang="EN-US"></span></strong></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif;mso-font-kerning:0pt" lang="EN-US"> </span></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;font-family:
宋体;mso-ascii-font-family:" times new roman";mso-fareast-font-family:宋体;
mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">近日,美高梅官网张海娇教授课题组在能源纳米材料领域的国际高水平期刊《</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt" lang="EN-US">Nano Energy</span><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
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mso-font-kerning:0pt" lang="EN-US">15.548</span><span style="font-size:12.0pt;line-height:
150%;font-family:宋体;mso-ascii-font-family:" times new roman";mso-fareast-font-family:
宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">)上发表题为《</span><a name="OLE_LINK214"><span style="font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif" lang="EN-US">Three-dimensional<span class="fontstyle01"><span style="mso-ansi-font-size:12.0pt;mso-bidi-font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif;color:windowtext"> MoS<sub>2</sub>/carbon sandwiched architecture for boosted lithium storage capability</span></span></span></a><span style="mso-bookmark:OLE_LINK214"></span><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
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"times new roman";mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">》的研究论文,硕士生吴程昊为第一作者,张海娇教授为通讯作者,上海大学为第一通讯作者单位。</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif;mso-font-kerning:0pt;mso-bidi-font-weight:
bold" lang="EN-US"> </span></p>
<p class="MsoNormal" style="text-align:center;line-height:150%" align="center"><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt;mso-no-proof:yes" lang="EN-US"><img src="../../Portals/717/1(43).jpg" alt="" width="600" height="524" /></span><span style="font-size:12.0pt;
line-height:150%;font-family:" times new roman",serif;mso-font-kerning:0pt" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-indent:25.6pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;font-family:
宋体;mso-ascii-font-family:" times new roman";mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";letter-spacing:.4pt;background:white">随着能源短缺和环境问题等的日益显著,锂离子电池成为主要的能量存储器件。</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman"">二硫化钼层状材料<span style="mso-no-proof:yes">在高能量密度锂电池中具有重要的研究意义,但该类材料普遍导电性差且存在较大的体积膨胀效应,从而导致电极结构的不稳定和循环寿命的快速衰减。虽然传统意义上的单层</span><span style="background:white">碳包覆可提高</span>电极材料的电导性和结构稳定性<span style="background:
white">,但裸露的那部分,仍然是不理想的。</span><span style="mso-no-proof:yes">针对以上关键问题,</span><span style="mso-font-kerning:0pt">张海娇教授课题组<span style="mso-no-proof:yes">通过</span>合理的实验设计和优化,在聚吡咯衍生的碳纳米管上生长二硫化钼纳米片的同时,成功实现了外层碳的均匀连续包覆,从而可获得电化学性能优异的氮掺杂的二硫化钼</span></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif" lang="EN-US">/</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
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mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman"">碳三明治型复合纳米材料</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-hansi-font-family:"times new roman";mso-bidi-font-family:
"times new roman";letter-spacing:.4pt;background:white">(</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-fareast-font-family:宋体;letter-spacing:.4pt;background:white" lang="EN-US">PCN@MoS<sub>2</sub>@C</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-hansi-font-family:"times new roman";mso-bidi-font-family:
"times new roman";letter-spacing:.4pt;background:white">)</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman"">。该中空管状结构可有效地缓冲锂离子脱嵌过程中导致的体积膨胀;更重要的是,<span style="color:black;mso-themecolor:text1">具有扩大层间距(</span></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
color:black;mso-themecolor:text1" lang="EN-US">0.98 nm</span><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
"times new roman";mso-bidi-font-family:"times new roman";color:black;
mso-themecolor:text1">)的超薄</span><span style="font-size:12.0pt;
line-height:150%;font-family:" times new roman",serif;color:black;mso-themecolor:
text1" lang="EN-US">MoS<sub>2</sub></span><span style="font-size:12.0pt;line-height:150%;
font-family:宋体;mso-ascii-font-family:" times new roman";mso-fareast-font-family:
宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";color:black;mso-themecolor:text1">纳米片被限域在两个不同的导电碳层之间,提高离子传输和电导的同时,也稳定了电极的结构。实验结果和密度泛函理论计算表明,这种独特三明治型新颖结构的构筑,有效提升了锂离子在多次充放电过程的反应动力学,从而获得了优异的储锂性能。</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
color:black;mso-themecolor:text1" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%;tab-stops:28.0pt 56.0pt 84.0pt 112.0pt 140.0pt 168.0pt 196.0pt 224.0pt 252.0pt 280.0pt 308.0pt 336.0pt;
mso-layout-grid-align:none;text-autospace:none"><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
"times new roman";mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">该工作由上海大学、澳大利亚皇家墨尔本理工大学和东华大学共同合作完成,得到了国家自然科学基金委、上海市教委和科委等的资助和支持。</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-align:left;text-indent:24.0pt;
mso-char-indent-count:2.0;line-height:150%;mso-pagination:widow-orphan" align="left"><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman";
color:black;mso-themecolor:text1;mso-font-kerning:0pt">论文链接:</span><span lang="EN-US"><a href="https://doi.org/10.1016/j.nanoen.2019.104061" target="_blank" title="Persistent link using digital object identifier"><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif">https://doi.org/10.1016/j.nanoen.2019.104061</span></a></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-fareast-font-family:"times new roman";color:blue;mso-font-kerning:0pt" lang="EN-US"></span></p>
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<span lang="EN-US"><a href="https://doi.org/10.1016/j.nanoen.2019.104061" target="_blank" title="Persistent link using digital object identifier"><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman","serif""></span></a></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman","serif";
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